The Neoproterozoic Port Askaig Formation contains widespread pyrite within many diamictite beds, across Scotland and Ireland. The quantity of pyrite is anomalous for coarse-grained rocks, especially in rocks deposited at a time when seawater contained low sulphate levels owing to a continental ice cover, which inhibited weathering. Sulphur isotope compositions evolve from lightest values (down to −3.1‰) at the base of the formation to highly positive compositions in the overlying Bonahaven Dolomite (mean +44.8‰). This trend is consistent with progressive utilization of available sulphate by closed-system microbial sulphate reduction. Together with records from other contemporary diamictite successions, there emerges a picture of global microbial activity during Neoproterozoic ‘Snowball Earth’ glaciation.
Supplementary material: Details of the sulphur isotopic composition are given at https://doi.org/10.6084/m9.figshare.c.3768959.
- Received November 28, 2016.
- Revision received March 24, 2017.
- Accepted March 27, 2017.
- © 2017 The Author(s)